Molecular Orbital Theory and Frontier Orbitals for Organic Chemistry

Molecular orbital (MO) theory, with its associated concepts of conjugation, aromaticity and hyperconjugation (along with the stereoelectronic effects based on frontier orbital approximations as a simplified version of perturbation theory) is an essential, fundamental and foundational topic for all students of organic chemistry and a core focus of interest. Organic chemists therefore frequently need simple and qualitative (yet quantifiable) explanations based on molecular orbital-based reasoning. This book aims to give readers a practical and deeper understanding of long-known concepts in MO theory and demonstrates how to formulate new ones, by simple arguments based on perturbation molecular orbital theory. It is written at a level that is designed to suit everyone from the undergraduate through to graduate and researcher level. Many in-chapter problems are included with detailed worked solutions, reinforcing the main themes in the text and so that students can test their learning immediately while reading through the chapters.

Molecular Orbital Theory and Frontier Orbitals for Organic Chemistry is written primarily for undergraduate and graduate-level students, teachers and researchers of organic chemistry, and to a wider circle of chemists who wish to quickly get acquainted with the important aspects in this field. The approach presented in this book aims to be distinct, practical and is highly pedagogical, tested by the authors teaching experience over decades and written at a level designed to suit everyone from the undergraduate to the research level.